Close This Page |
|
|
|
|
|
|
|
|
MATERIAL SAFETY DATA SHEET |
|
|
|
|
|
|
|
|
|
|
|
|
SECTION 1 - PRODUCT
SOURCE AND IDENTITY |
|
|
|
|
|
|
|
Supplier identity and
address |
|
|
Product description: Date: Jan. 18, 2003 |
|
|
|
|
Doodle Products |
|
|
|
|
|
|
Name:
Doodle |
|
|
|
|
|
|
|
|
|
P.O. Box 365 |
|
|
|
Purpose:
Helps clean up soiled pet areas |
|
|
|
|
|
Pacific, MO 63069 |
|
|
|
Proprietary
Formula Code: DPD |
|
|
|
|
|
|
|
|
|
|
|
Transportation emergency: Not applicable |
|
|
|
Product information: |
636-257-7005 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
SECTION
2 - SHIPPING CLASSIFICATION |
|
|
|
|
|
|
|
|
|
|
|
Proper Shipping Name, Hazard Class, UN/NA Number Packing Group, Emergency Response Guide Number |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Not regulated |
|
|
|
|
|
|
|
Labels required per 49 CFR 172.101: |
|
|
|
None |
|
|
|
|
|
|
|
|
Qualifies for
"Limited quantity" per 49 CFR 173.154: |
|
|
|
|
|
|
|
|
|
Not applicable |
|
|
|
|
|
|
|
Reportable Quantity ("RQ") per 49
CFR172.101: |
|
None or not
possible in one non-bulk package |
|
|
|
|
|
|
|
|
|
|
SECTION 3- SAFETY RATINGS
AND HAZARDOUS INGREDIENT INFORMATION |
|
|
|
|
Reporting required by Title III Sec 313,
40CFR 372, 29CFR 1910.1200 |
|
Exposure Limit Values |
|
|
CAS# |
|
313 |
|
Material or Component |
|
|
% |
RQ# |
|
TWA STEL |
|
|
|
|
|
Contains natural enzymes which the
FDA has approved as GRAS*. |
|
|
|
|
|
|
|
|
|
*Generally Recognized as Safe |
|
|
|
|
|
|
|
Product also contains non regulated
detergents which may contribute to eye and skin irritation. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
No component is listed in "Threshold
Limit Values and Biological Exposure indices for 2002" from ACGIH except
as |
|
|
as noted above. Components listed in TITLE
III SEC 313 (EPCRA) are indicated by
"Yes" above. |
|
|
|
|
California criteria: Constituents qualifying
as hazardous materials, substances or waste, other than above, if any, |
|
|
have been neutralized/ denatured to a non
hazardous condition. Regulations referenced: California Health & Safety |
|
|
Code Ch 6.95 Sec 25501(k)&(l), CCR Title
22, Sec 66261.21-.24,and Appendix X of 22CCR Chapter 11, Article 4. |
|
|
Emergency overview: |
|
Neutral solution. Keep
out of eyes and off of skin. |
|
|
|
|
|
|
|
|
|
|
|
|
Use standard industrial
good practices. |
|
|
|
|
|
|
|
|
Hazard Categories: |
Health |
Fire |
|
Pressure |
Reactivity |
Reference 49 CFR 171.8, |
|
|
|
Immediate |
|
|
Yes |
|
No |
|
No |
|
No |
OSHA 29 CFR 1910.1200 and |
|
|
Delayed |
|
|
|
No |
|
XXX |
|
XXX |
|
XXX |
SARA 302/311/312/313. |
|
|
|
HMIS Hazard ratings: Health
1 Fire 0
Instability 0 Other
B (Glasses, gloves) |
|
|
|
|
|
NFPA 704 Hazard Ratings: Health 1
Flammability 0 Reactivity
0 Other NA |
|
|
|
|
|
|
|
Hazard Ratings: Least:
0 Slight: 1
Moderate: 2 High:
3 Extreme: 4 |
|
|
|
|
|
|
|
Threshold limit value: |
Not established
on product. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
TOSCA Status: All ingredients listed |
|
|
CERCLA RQ:
See Sec 2. |
|
|
|
|
|
|
California Prop. 65: None |
|
|
|
|
|
|
|
|
|
SECTION 4 - PHYSICAL AND CHEMICAL
PROPERTIES |
|
|
|
|
|
Appearance: |
|
|
Slightly
cloudy amber liquid |
Flash point deg. F (cc): |
|
|
None |
|
|
Odor: |
|
|
|
Slight, characteristic |
|
Initial boiling point deg. C: |
|
ND |
|
|
|
Specific gravity: |
|
|
>1 |
|
|
|
|
Vapor pressure 20 deg C: |
|
ND |
|
|
|
pH reaction: |
|
|
6-8 |
|
|
|
|
Freezing point deg. C: |
|
|
ND |
|
|
|
% phosphorous: |
|
|
|
|
None |
|
|
|
Solubility in
water: |
|
|
|
|
|
100% |
|
|
VOC Content: |
|
|
|
35 g/l |
|
|
|
|
|
|
|
Reproductive implications: |
|
|
None |
|
|
|
|
|
|
|
|
|
|
|
Ingredients on cancer lists: |
|
|
None |
|
|
|
|
|
|
|
|
|
|
|
California Rule 102 (66): |
Contains no photo
chemically active materials. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
SECTION 5 - SAFE HANDLING AND STORAGE |
|
|
|
|
|
|
General |
|
|
Approximately neutral pH
enzyme cleaner. Keep out of eyes and off of skin. |
|
|
|
|
|
Do not breathe mists or aerosols.
Use standard industrial good practices. |
|
|
|
|
|
Wipe up spills immediately as they may be slippery. Store in a cool
place for longer shelf life. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Protective equipment |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eyes |
Safety glasses or goggles should be worn if there is possibility of eye
contact. |
|
|
|
|
|
Skin |
Impermeable gloves such as rubber, PVC or
neoprene are recommended. |
|
|
|
|
|
Respiratory protection |
|
|
None
normally required. If risk of inhalation occurs, select and |
|
|
|
use equipment
according to OSHA/NIOSH guidelines for nuisance mists. |
|
|
|
|
|
Ventilation |
A well ventilated work environment is
recommended. |
|
|
|
|
|
|
|
|
Other |
None |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
SECTION 6- HEALTH SAFETY DATA |
|
|
|
|
|
|
|
|
Effects of chronic over exposure |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Eyes |
|
Can cause reversible irritation. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Skin |
|
Can cause reversible irritation from
repeated exposure. Some sensitization to the |
|
|
|
|
|
|
enzymes is known. Discontinue use if this
occurs. |
|
|
|
|
|
|
|
|
Inhalation |
|
May aggravate respiratory ailments. Mists
may be irritating to breathing passages. |
|
|
|
Ingestion |
|
Not a
likely source of chronic exposure. |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
SECTION 7 - PHYSICAL STABILITY AND
REACTIVITY DATA |
|
|
|
|
|
|
|
Explosive limits |
|
|
|
Flash point: |
|
|
See Sec 4 |
|
|
|
|
|
|
Upper
None |
Lower |
None |
Conditions to avoid: Storage above 95'F. |
|
|
|
|
Chemical |
|
Stable |
|
|
Hazardous decomposition products: |
|
|
|
|
|
|
stability |
|
|
|
|
|
|
Oxides of carbon and
nitrogen if burned |
|
|
|
|
|
Hazardous |
|
|
|
|
Incompatibility: |
None known |
|
|
|
|
polymerization |
|
Cannot occur |
|
|
|
|
|
|
|
|
SECTION 8- EMERGENCY RESPONSE PROCEDURES |
|
|
|
|
|
|
Fire |
|
Extinguishing media |
|
Use equipment appropriate to the main cause
of the fire. |
|
|
|
|
|
Special procedures |
|
None |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Unusual hazards |
|
|
None |
|
|
|
|
|
|
|
|
|
|
|
First |
|
Eyes |
Flush with water for at least 15 min. Seek
medical attention. See Sec. 6. |
|
|
|
|
Aid |
|
Skin |
|
Wash exposed skin with soap and water until
gone. Remove affected |
|
|
|
|
|
|
|
|
clothes rinse off product and wash clothes before reuse. |
|
|
|
|
|
|
|
|
Inhalation |
|
If affected, remove individual to fresh air,
get medical attention at |
|
|
|
|
|
|
|
|
|
once if there is any
discomfort. |
|
|
|
|
|
|
|
|
|
|
|
Ingestion |
|
Dilute by giving large amounts of milk or
water. Get medical |
|
|
|
|
|
|
|
|
|
|
attention immediately. Do not induce
vomiting. |
|
|
|
|
|
|
|
Spills |
Small / large spill |
|
Small amounts
may be flushed to drain. Comply with federal, |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
state and local regulations on
reporting spills. Floors may be |
|
|
|
|
|
|
|
slippery. |
|
|
|
|
|
|
|
|
Keep out of waterways and storm
sewers. |
|
|
|
|
|
|
|
|
|
|
|
|
|
Product as made does not qualify as an
"Unlisted Hazardous Waste" for disposal situations. |
|
|
|
|
Information presented herein has been
compiled from sources considered to be accurate and reliable, but is not |
|
|
guaranteed to be so. Since conditions of
use are beyond our control we make no warranties, expressed or implied. |
|
|
MSDS prepared by: R.N. Miller 1-800-342-3577 |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
Close This Page |