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              MATERIAL SAFETY DATA SHEET          
          SECTION 1 - PRODUCT SOURCE AND IDENTITY        
  Supplier identity and address      Product description:                   Date:  Jan. 18, 2003  
  Doodle Products          Name:        Doodle            
  P.O. Box 365    Purpose:    Helps clean up soiled pet areas  
  Pacific, MO 63069        Proprietary Formula         Code:  DPD                  
 Transportation emergency: Not applicable      Product information: 636-257-7005          
                    SECTION 2 - SHIPPING CLASSIFICATION                  
    Proper Shipping Name, Hazard Class, UN/NA Number Packing Group, Emergency Response Guide Number                      
                                   
                  Not regulated          
 Labels required per 49 CFR 172.101:       None            
 Qualifies for "Limited quantity" per 49 CFR 173.154:                   Not applicable          
 Reportable Quantity ("RQ") per 49 CFR172.101:  None or not possible in one non-bulk package                
                    SECTION 3- SAFETY RATINGS AND HAZARDOUS INGREDIENT INFORMATION    
 Reporting required by Title III Sec 313, 40CFR 372, 29CFR 1910.1200       Exposure Limit Values
 CAS#   313    Material or Component        % RQ#   TWA       STEL  
  Contains natural enzymes which the FDA has approved as GRAS*.          
  *Generally Recognized as Safe  
  Product also contains non regulated detergents which may contribute to eye and skin irritation.  
                                 
 No component is listed in "Threshold Limit Values and Biological Exposure indices for 2002" from ACGIH except as
 as noted above. Components listed in TITLE III SEC 313 (EPCRA) are indicated  by "Yes" above.   
 California criteria: Constituents qualifying as hazardous materials, substances or waste, other than above, if any,
 have been neutralized/ denatured to a non hazardous condition. Regulations referenced: California Health & Safety
 Code Ch 6.95 Sec 25501(k)&(l), CCR Title 22, Sec 66261.21-.24,and Appendix X of 22CCR Chapter 11, Article 4.
 Emergency overview:    Neutral solution. Keep out of eyes and off of skin.          
          Use standard industrial good practices.            
 Hazard Categories:   Health       Fire    Pressure Reactivity Reference 49 CFR 171.8,  
     Immediate     Yes   No   No   No  OSHA 29 CFR 1910.1200 and
     Delayed       No   XXX   XXX   XXX  SARA 302/311/312/313.  
 HMIS Hazard ratings:  Health  1    Fire     0      Instability  0     Other  B (Glasses, gloves)      
 NFPA 704 Hazard Ratings: Health  1  Flammability  0  Reactivity  0   Other  NA          
 Hazard Ratings:    Least:  0     Slight:  1     Moderate:  2     High:  3  Extreme:  4          
 Threshold limit value: Not established on product.                       
 TOSCA Status: All ingredients listed      CERCLA RQ:  See Sec 2.        
 California Prop. 65:  None    
           SECTION 4 - PHYSICAL AND CHEMICAL PROPERTIES      
 Appearance:     Slightly cloudy amber liquid  Flash point deg. F (cc):     None
 Odor:       Slight, characteristic    Initial boiling point deg. C:   ND  
 Specific gravity:     >1          Vapor pressure 20 deg C:    ND  
 pH reaction:     6-8          Freezing point deg. C:     ND  
 % phosphorous:         None        Solubility in water:           100%
 VOC Content:       35 g/l        
 Reproductive implications:      None                  
 Ingredients on cancer lists:      None                  
 California Rule 102 (66): Contains no photo chemically active materials.          
           SECTION 5 - SAFE HANDLING AND STORAGE        
  General     Approximately neutral pH enzyme cleaner. Keep out of eyes and off of skin.  
  Do not breathe mists or aerosols. Use standard industrial good practices.  
  Wipe up spills immediately as they may be slippery. Store in a cool place for longer shelf life.                          
  Protective equipment                            
  Eyes  Safety glasses or goggles should be  worn if there is possibility of eye contact.      
  Skin  Impermeable gloves such as rubber, PVC or neoprene are recommended.      
  Respiratory protection     None normally required. If risk of inhalation occurs, select and   
                                use equipment according to OSHA/NIOSH guidelines for nuisance mists.      
  Ventilation  A well ventilated work environment is recommended.            
  Other   None                            
                SECTION 6-  HEALTH SAFETY DATA            
  Effects of chronic over exposure                        
  Eyes    Can cause reversible irritation.                            
  Skin    Can cause reversible irritation from repeated exposure. Some sensitization to the  
       enzymes is known. Discontinue use if this occurs.            
  Inhalation    May aggravate respiratory ailments. Mists may be irritating to breathing passages.  
  Ingestion    Not a likely source of chronic exposure.                            
                                   
             SECTION 7 - PHYSICAL STABILITY AND REACTIVITY DATA        
    Explosive limits        Flash point:     See Sec 4        
  Upper   None  Lower None  Conditions to avoid: Storage above 95'F.  
  Chemical    Stable      Hazardous decomposition products:        
    stability             Oxides of carbon and nitrogen if burned      
  Hazardous          Incompatibility:  None known  
     polymerization    Cannot occur     
          SECTION 8- EMERGENCY RESPONSE PROCEDURES        
 Fire    Extinguishing media    Use equipment appropriate to the main cause of the fire.  
     Special procedures    None                  
                                   
     Unusual hazards      None                  
 First    Eyes  Flush with water for at least 15 min. Seek medical attention. See Sec. 6.    
 Aid    Skin    Wash exposed skin with soap and water until gone. Remove affected    
        clothes rinse off  product and wash clothes before reuse.        
     Inhalation    If affected, remove individual to fresh air, get medical attention at     
          once if there is any discomfort.              
     Ingestion    Dilute by giving large amounts of milk or water. Get medical       
           attention immediately. Do not induce vomiting.          
 Spills  Small / large spill   Small amounts may be flushed to drain. Comply with federal,                    
    state and local regulations on reporting spills. Floors may be  
    slippery.  
      Keep out of waterways and storm sewers.  
     
     Product as made does not qualify as an "Unlisted Hazardous Waste" for disposal situations.    
  Information presented herein has been compiled from sources considered to be accurate and reliable, but is not
  guaranteed to be so. Since conditions of use are beyond our control we make no warranties, expressed or implied.
 MSDS prepared by: R.N. Miller 1-800-342-3577                    
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